S. Ogiri et al., IN-SITU PHOTOPOLYMERIZATION BEHAVIOR OF A CHIRAL LIQUID-CRYSTALLINE MONOMER SHOWING A FERROELECTRIC PHASE, Macromolecules, 31(6), 1998, pp. 1728-1734
The in situ photopolymerization behavior of a ferroelectric Liquid-cry
stalline (FLC) monomer possessing a chiral moiety is discussed on the
basis of molecular alignment in the liquid-crystalline phase. In an ea
rly stage of polymerization, the polymerizability of the FLC monomers
was highest in the ferroelectric chiral smectic C (SmC) phase in the
absence of an external electric field. The polymerization behavior was
found to depend mainly on the molecular alignment in the initial stat
e of polymerization. In contrast, in the late stage of polymerization,
the polymerization behavior of the FLC monomers was governed by their
diffusion rather than their alignment. This may be due to the change
in the phase structure during in situ polymerization. In addition, the
alignment of the photopolymerized FLC was evaluated by optical polari
zing microscopy. It was found that the application of an electric fiel
d to the FLC monomer resulted in the appearance of the immobilized SmC
phase, in which all mesogens of the resulting FLC polymer were align
ed in one direction, leading to the formation of a monodomain of LC ph
ase.