Hz. Zhuang et al., ARE GUGGENHEIM FORMULAS AND LANDAU THEORY STILL APPLICABLE TO EXPANDED LIQUID-METALS, Physica. B, Condensed matter, 245(2), 1998, pp. 110-113
In the present work, we have found that Guggenheim formulae are still
applicable to the liquid-vapor coexistence curves of expanded fluid me
tals only by adjusting their coefficients rather than exponents. In ad
dition, the equation of state of expanded liquid cesium has been deriv
ed based on Landau theory of continuous phase transitions including th
e sixth-order term of the order parameter. Both the equation of state
and the coexistence curves obtained are in good agreement with experim
ental data. (C) 1998 Elsevier Science B.V. All rights reserved.