The deformation potentials a, b and d for GaAs have been determined fr
om polarized photoluminescence measurements upon a set of epitaxially
grown strained GaAs structures possessing varying levels of compressiv
e biaxial lattice strain. X-ray diffraction measurements yield values
for the degree of lattice strain while the polarized photoluminescence
measurements permit a separate determination to be made of the heavy
hole and light hole band energies. Correlation of these data allows fo
r the determination of the deformation potentials within the context o
f the orbital-strain Hamiltonian. (C) 1998 Published by Elsevier Scien
ce B.V.