Xs. Wang et al., EFFECT OF A STM TIP ON THE SURFACE-DIFFUSION MEASUREMENT - A MONTE-CARLO STUDY, Physical review. B, Condensed matter, 57(12), 1998, pp. 7275-7280
Monte Carlo simulations are performed to study the effect of an electr
ic field on the surface diffusion of adatoms in a method that measures
scanning tunneling microscopy tunneling-current fluctuations. The cor
relation function of the tunneling-current fluctuations is proportiona
l to the adatom density fluctuation. Diffusion coefficients are invers
ely proportional to the time constant of the correlation function. Bot
h the shape of the correlation and the measured time constant are calc
ulated as a function of the ratio of the temperature to the characteri
stic electrostatic energy (i.e., strength of the electric field) and a
s a function of the initiating time of the measurement. The effect of
the field is more pronounced when the measurement is carried out in th
e early nonequilibrium time regime while the adatom density evolves to
wards its equilibrium distribution under the spatially dependent elect
rostatic potential due to the electric field.