Consideration is given to the possible mechanisms responsible for the
production of the atomic sodium tail of comet Hale-Bopp. It is shown t
hat both photosputtering and ion sputtering of nonvolatile dust grains
might not be the main driving force. Instead, the generation of impac
t vapor by collisional interaction between the cometary dust coma of m
icron-sized particles and the very small grains (VSGs) of 10-100 Angst
rom size could possibly account for the observations if a large amount
of VSGs existed in the coma region.