STUDIES ON THE REDUCING BEHAVIOR OF DIHYDROBIS(1-PYRAZOLYL)BORATE ANDPYRAZABOLE

Authors
DAS MK BHAUMIK A
Citation
Mk. Das et A. Bhaumik, STUDIES ON THE REDUCING BEHAVIOR OF DIHYDROBIS(1-PYRAZOLYL)BORATE ANDPYRAZABOLE, Indian journal of chemistry. Sect. B: organic chemistry, including medical chemistry, 36(11), 1997, pp. 1020-1024
Citations number
30
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Indian journal of chemistry. Sect. B: organic chemistry, including medical chemistry → ACNP
ISSN journal
03764699
Volume
36
Issue
11
Year of publication
1997
Pages
1020 - 1024
Database
ISI
SICI code
0376-4699(1997)36:11<1020:SOTRBO>2.0.ZU;2-3
Abstract
Dihydrobis(1-pyrazolyl)borate, [H2B(pz)(2)](-) (as its potassium and c opper(II) salts) and pyrazabole, H2B(mu-pz)(2)BH2(Hpz = pyrazole), hav e been investigated for their reducing behaviour towards a number of o rganic functional groups. They have been found to be efficient and in some cases selective reducing agents towards carbonyl groups in protic solvents. Many other functional groups remain unaffected. The results are also compared with those of butylamine-cyanoborane reported earli er.