GOLD(I) COMPLEX OF 7-DIPHENYLPHOSPHINO-2,4-DIMETHYL-1,8-NAPHTHYRIDINE(DPNAPY) AS A METALLOLIGAND FOR ENCAPSULATION OF METAL-IONS - CRYSTAL-STRUCTURES OF [AUCU(DPNAPY)(3)][CLO4](2) AND [AUCD(DPNAPY)(3)][CLO4](3)

Authors
CHAN WH CHEUNG KK MAK TCW CHE CM
Citation
Wh. Chan et al., GOLD(I) COMPLEX OF 7-DIPHENYLPHOSPHINO-2,4-DIMETHYL-1,8-NAPHTHYRIDINE(DPNAPY) AS A METALLOLIGAND FOR ENCAPSULATION OF METAL-IONS - CRYSTAL-STRUCTURES OF [AUCU(DPNAPY)(3)][CLO4](2) AND [AUCD(DPNAPY)(3)][CLO4](3), Journal of the Chemical Society. Dalton transactions, (6), 1998, pp. 873-874
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
6
Year of publication
1998
Pages
873 - 874
Database
ISI
SICI code
0300-9246(1998):6<873:GCO7>2.0.ZU;2-Z
Abstract
Reaction of dpnapy [dpnapy = 7-diphenylphosphino-2,4-dimethyl- 1,8-nap hthyridine] with [Au(tht)Cl] (tht = tetrahydrothiophene) in dichlorome thane afforded [Au(dpnapy)(3)](+), which shows a strong affinity towar ds Cu-I and Cd-II ions; crystal structures of [AuCu(dpnapy)(3)][ClO4]( 2) and [AuCd(dpnapy)(3)][ClO4](3) revealed that [Au(dpnapy)(3)](+) fun ctions as a metalloligand with the three naphthyridyl groups positione d in a trigonal fashion.