CAN-MEDIATED TANDEM 5-EXO-CYCLIZATION OF TERTIARY AMINOCYCLOPROPANES - NOVEL ACCELERATIVE EFFECT OF AN N-BENZYL GROUP FOR OXIDATIVE RING-OPENING

Authors
TAKEMOTO Y YAMAGATA S FURUSE S HAYASE H ECHIGO T IWATA C
Citation
Y. Takemoto et al., CAN-MEDIATED TANDEM 5-EXO-CYCLIZATION OF TERTIARY AMINOCYCLOPROPANES - NOVEL ACCELERATIVE EFFECT OF AN N-BENZYL GROUP FOR OXIDATIVE RING-OPENING, Chemical communications, (6), 1998, pp. 651-652
Citations number
26
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
6
Year of publication
1998
Pages
651 - 652
Database
ISI
SICI code
1359-7345(1998):6<651:CT5OTA>2.0.ZU;2-S
Abstract
Treatment of tertiary cyclopropylamines with cerium(IV) ammonium nitra te (CAN) gave ring-opened ketones and/or bicyclic secondary amines via an oxidative cyclopropane cleavage followed by a hydrogen abstraction or 5-exo radical cyclization: an N-benzyl group plays a crucial role in these reactions.