METAL-BOUND CHLORINE OFTEN ACCEPTS HYDROGEN-BONDS

Authors
AULLON G BELLAMY D BRAMMER L BRUTON EA ORPEN AG
Citation
G. Aullon et al., METAL-BOUND CHLORINE OFTEN ACCEPTS HYDROGEN-BONDS, Chemical communications, (6), 1998, pp. 653-654
Citations number
18
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
6
Year of publication
1998
Pages
653 - 654
Database
ISI
SICI code
1359-7345(1998):6<653:MCOAH>2.0.ZU;2-L
Abstract
Analysis of 6624 crystallographically characterised hydrogen bonds con taining M-Cl, C-Cl or Cl- and either HO or HN groups show that M-Cl mo ieties are good, anisotropic hydrogen-bond accepters forming hydrogen bonds similar in length to those of the chloride anion, while C-Cl moi eties are very poor hydrogen-bond accepters.