CHLORINE ABSTRACTION BY LASER PYROLYSIS OF W(CO)(6) - A MILD ROUTE TOGAS-PHASE ORGANIC RADICAL CHEMISTRY

Authors
ALLEN GR RENNER ND RUSSELL DK
Citation
Gr. Allen et al., CHLORINE ABSTRACTION BY LASER PYROLYSIS OF W(CO)(6) - A MILD ROUTE TOGAS-PHASE ORGANIC RADICAL CHEMISTRY, Chemical communications, (6), 1998, pp. 703-704
Citations number
20
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
6
Year of publication
1998
Pages
703 - 704
Database
ISI
SICI code
1359-7345(1998):6<703:CABLPO>2.0.ZU;2-P
Abstract
SF6-photosensitised IR laser pyrolysis of W(CO)(6) in the gas phase at moderate temperatures leads to unsaturated W(CO)(n) species; these pr ove to be very effective and selective abstractors of Cl atoms from a wide range of organic substrates, and offer a low energy and clean rou te into gas phase organic radical chemistry.