SYNTHESES OF 6,19-OXIDO-BRIDGED ANALOGS OF 11-BETA,17-ALPHA-DIHYDROXYPROGESTERONE AND 11-KETO-17-ALPHA-HYDROXYPROGESTERONE

Citation
M. Joselevich et al., SYNTHESES OF 6,19-OXIDO-BRIDGED ANALOGS OF 11-BETA,17-ALPHA-DIHYDROXYPROGESTERONE AND 11-KETO-17-ALPHA-HYDROXYPROGESTERONE, Anales de la Asociacion Quimica Argentina, 85(3-4), 1997, pp. 117-121
Citations number
7
Categorie Soggetti
Chemistry
ISSN journal
03650375
Volume
85
Issue
3-4
Year of publication
1997
Pages
117 - 121
Database
ISI
SICI code
0365-0375(1997)85:3-4<117:SO6AO1>2.0.ZU;2-0
Abstract
11 beta, 17 alpha-Dihydroxy-6,19-oxidoprogesterone (1) and 11-keto-17 alpha-hydroxy-6,19-oxidoprogesterone (2) were synthesized from readily available materials. C-19 functionalization was accomplished with the mercuric oxide/iodine system under irradiation with visible light.