BIS(TRIISOPROPYLSILOXYINDENYL)ZIRCONOCENES

Authors
LUTTIKHEDDE HJG LEINO R LEHTONEN A NASMAN JH
Citation
Hjg. Luttikhedde et al., BIS(TRIISOPROPYLSILOXYINDENYL)ZIRCONOCENES, Journal of organometallic chemistry, 555(1), 1998, pp. 127-134
Citations number
32
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
555
Issue
1
Year of publication
1998
Pages
127 - 134
Database
ISI
SICI code
0022-328X(1998)555:1<127:B>2.0.ZU;2-A
Abstract
The synthesis and characterization of 1- and 2-triisopropylsiloxy subs tituted bis(indenyl) zirconocenes is reported. The molecular structure s of enebis(2-(triisopropylsiloxy)-1-indenyl)]zirconium dichloride (6) and pylsiloxy)-4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride (8) have been determined and reveal that complex (6) crystallizes in the indenyl-forward (II) conformation while (8) adopts the indenyl-backwar d (Y) conformation. (C) 1998 Elsevier Science S.A. All rights reserved .