BEHAVIOR OF A POLYMER-CHAIN IN A CRITICAL BINARY SOLVENT

Citation
M. Stapper et Ta. Vilgis, BEHAVIOR OF A POLYMER-CHAIN IN A CRITICAL BINARY SOLVENT, Europhysics letters, 42(1), 1998, pp. 7-12
Citations number
14
Categorie Soggetti
Physics
Journal title
ISSN journal
02955075
Volume
42
Issue
1
Year of publication
1998
Pages
7 - 12
Database
ISI
SICI code
0295-5075(1998)42:1<7:BOAPIA>2.0.ZU;2-S
Abstract
We present a field-theoretic renormalization group analysis of a polym er chain immersed in a binary good solvent close to its critical demix ing point. We first show that this problem can be mapped on a bicritic al field theory, i.e. a (phi(2))(2)-model with a mass anisotropy. This implies that the end-to-end distance of the polymer is now controlled by a new critical exponent nu(B) related to the quadratic mass anisot ropy operator B. To show this, we solve the RG equation and calculate explicitly the exponents and the mean end-to-end length of the chain.