ENANTIOPURE 3-AMIDO OR 3,3'-BISAMIDO SUBSTITUTED 1,1'-BI-2-NAPHTHOLS BY ANIONIC FRIES REARRANGEMENTS

Citation
Mr. Dennis et S. Woodward, ENANTIOPURE 3-AMIDO OR 3,3'-BISAMIDO SUBSTITUTED 1,1'-BI-2-NAPHTHOLS BY ANIONIC FRIES REARRANGEMENTS, Journal of the Chemical Society. Perkin transactions. I, (6), 1998, pp. 1081-1085
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
ISSN journal
0300922X
Issue
6
Year of publication
1998
Pages
1081 - 1085
Database
ISI
SICI code
0300-922X(1998):6<1081:E3O3S1>2.0.ZU;2-N
Abstract
Mono- or di-carbamates of 1,1'-bi-2-naphthol ortholithiate with (BuLi) -Li-s-TMEDA, The resulting anions may either be captured by MeI or all owed to undergo anionic Fries rearrangement, Thus generalised two-step routes to mono-and di-(3-alkyl) or -(3-amido) substituted 2,2'-binapt hols is demonstrated.