M. Alagia et al., MAGNETIC ANALYSIS OF SUPERSONIC BEAMS OF ATOMIC OXYGEN, NITROGEN, ANDCHLORINE GENERATED FROM A RADIOFREQUENCY DISCHARGE, Israel Journal of Chemistry, 37(4), 1997, pp. 329-342
Supersonic beams of oxygen, nitrogen, and chlorine atoms and of metast
able oxygen and nitrogen molecules produced from a high-pressure radio
frequency discharge beam source have been characterized by coupling ve
locity selection with magnetic analysis in the transmission mode. The
present work leads to the determination of the relative populations of
the electronic states of the species in the produced beams, showing t
hat estimates of the populations from plasma temperatures or final tra
nslational temperatures could bring on incorrect conclusions.