SPECTROSCOPIC PROPERTIES OF THE VANADIUM(III) TRIS(METAPHOSPHATE), V(PO3)(3)

Authors
ROJO JM MESA JL LEZAMA L ROJO T OLAZCUAGA R GUILLEN F
Citation
Jm. Rojo et al., SPECTROSCOPIC PROPERTIES OF THE VANADIUM(III) TRIS(METAPHOSPHATE), V(PO3)(3), Annales de chimie, 23(1-2), 1998, pp. 107-111
Citations number
15
Categorie Soggetti
Chemistry,"Material Science
Journal title
Annales de chimie → ACNP
ISSN journal
01519107
Volume
23
Issue
1-2
Year of publication
1998
Pages
107 - 111
Database
ISI
SICI code
0151-9107(1998)23:1-2<107:SPOTVT>2.0.ZU;2-G
Abstract
A vanadium(III) tris(metaphosphate) compound has been synthesized and characterized. The compound crystallises in the monoclinic space group Ic with lattice parameters a= 10.615(2), b= 19.095(4), c= 9.432(1) An gstrom, beta= 97.94(1) degrees. IR and UV-V studies confirm a chain st ructure for this compound. The ESR powder spectrum shows a weak signal belonging to the V3+ ions. The D parameter value has been estimated b etween 2 and 8 cm(-1).