Normal-incidence operation, based on TE electron intersub-band transit
ions in n-type unipolar optoelectronic devices, would have a wide rang
e of applications. However, TE intersub-band transitions are generally
accepted to be (nearly) forbidden in direct gap conduction-band quant
um wells, The paper describes 14-band k.p effective mass theory calcul
ations of TE electron intersub-band matrix elements in n-type, direct-
gap systems, to determine the extent to which TE intersub-band transit
ion strengths can be enhanced by choice of quantum well shape and comp
osition, The possibility of enhanced TE:TM transition strength ratios,
owing to remote-band contributions to the matrix elements, is describ
ed but no significant enhancement of matrix elements over predictions
of the single-band model is calculated for conventional quantum wells.
A mechanism is presented for nonsquare wells which is suggested to en
hance TE:TM transition strength ratio based on remote-band coupling ef
fects through bulk momentum matrix elements P-1 and Q.