ELECTROCHEMICAL FLUORINATION OF BETA-DICARBONYL COMPOUNDS USING P-IODOTOLUENE DIFLUORIDE AS A MEDIATOR

Authors
HARA S HATAKEYAMA T CHEN SQ ISHII K YOSHIDA M SAWAGUCHI M FUKUHARA T YONEDA N
Citation
S. Hara et al., ELECTROCHEMICAL FLUORINATION OF BETA-DICARBONYL COMPOUNDS USING P-IODOTOLUENE DIFLUORIDE AS A MEDIATOR, Journal of fluorine chemistry, 87(2), 1998, pp. 189-192
Citations number
29
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of fluorine chemistry → ACNP
ISSN journal
00221139
Volume
87
Issue
2
Year of publication
1998
Pages
189 - 192
Database
ISI
SICI code
0022-1139(1998)87:2<189:EFOBCU>2.0.ZU;2-M
Abstract
The selective and direct introduction of the fluorine atom into the al pha-position of beta-dicarbonyl compounds was electrochemically achiev ed using iodotoluene difluoride as the mediator. The resulting alpha-f luoro-beta-dicarbonyl compounds are important building blocks for biol ogically active compounds. (C) 1998 Elsevier Science S.A.