THE THIOETHER GROUP - A GOOD SUBSTITUTE F OR OXIDATIVE FLUORINATION

Authors
LAURENT E MARQUET B ROZE C VENTALON F
Citation
E. Laurent et al., THE THIOETHER GROUP - A GOOD SUBSTITUTE F OR OXIDATIVE FLUORINATION, Journal of fluorine chemistry, 87(2), 1998, pp. 215-220
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of fluorine chemistry → ACNP
ISSN journal
00221139
Volume
87
Issue
2
Year of publication
1998
Pages
215 - 220
Database
ISI
SICI code
0022-1139(1998)87:2<215:TTG-AG>2.0.ZU;2-3
Abstract
Regiospecific monofluorinations of alpha-thio alpha-arylesters and alp ha-thioacids were obtained by anodic and/or chemical oxidation in fluo rinating media. This procedure provided a convenient synthesis of alph a-fluoroesters via the CS bond cleavage induced by anodic process whil e chemical or electrochemical oxidation of alpha-thioacids underwent a fluoro decarboxylation, affording alpha-fluorothioethers. (C) 1998 El sevier Science S.A.