Dl. Jiang et al., CA2-( INDUCED FE(CN)(6)(3)4-) ELECTRON-TRANSFER AT PT SUPPORTED BLM ELECTRODE/, Bioelectrochemistry and bioenergetics, 44(2), 1998, pp. 285-288
The effect of Ca2+ on the electron transfer of Fe(CN)(6)(3-/4-) couple
at Pt supported lecithin (PC)/cholesterol (CH) bilayer lipid membrane
(BLM) electrode has been studied by voltammetry and ac impedance spec
troscopy. Experimental results suggest that the interaction of Ca2+ wi
th the BLM can open some kind of channel for Fe(CN)(6)(3-/4-) ions, al
lowing increased access of the redox couple to the electrode surface.
This phenomenon may be related to the Ca2+ regulation or activation ef
fect of ion channel in some biomembranes. (C) 1998 Elsevier Science S.
A.