SYNTHETIC STUDIES ON THE INGENANE DITERPENES - CONSTRUCTION OF AN ABCTRICYCLE EXHIBITING TRANS-INTRABRIDGEHEAD STEREOCHEMISTRY

Authors
RIGBY JH HU JD HEEG MJ
Citation
Jh. Rigby et al., SYNTHETIC STUDIES ON THE INGENANE DITERPENES - CONSTRUCTION OF AN ABCTRICYCLE EXHIBITING TRANS-INTRABRIDGEHEAD STEREOCHEMISTRY, Tetrahedron letters, 39(16), 1998, pp. 2265-2268
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
16
Year of publication
1998
Pages
2265 - 2268
Database
ISI
SICI code
0040-4039(1998)39:16<2265:SSOTID>2.0.ZU;2-R
Abstract
Intramolecular, metal-promoted [6 pi+4 pi] cycloaddition followed by a lkoxide accelerated 1,5-H sigmatropy affords a functionalized ingenane tricycle possessing the critical in,out-intrabridgehead stereochemica l relationship. (C) 1998 Elsevier Science Ltd. All rights reserved.