THIACALIXARENES - SYNTHESIS AND STRUCTURAL-ANALYSIS OF THIACALIX[LT]ARENE AND OF P-TERT-BUTYLTHIACALIX[4]ARENE

Authors
AKDAS H BRINGEL L GRAF E HOSSEINI MW MISLIN G PANSANEL J DECIAN A FISCHER J
Citation
H. Akdas et al., THIACALIXARENES - SYNTHESIS AND STRUCTURAL-ANALYSIS OF THIACALIX[LT]ARENE AND OF P-TERT-BUTYLTHIACALIX[4]ARENE, Tetrahedron letters, 39(16), 1998, pp. 2311-2314
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
16
Year of publication
1998
Pages
2311 - 2314
Database
ISI
SICI code
0040-4039(1998)39:16<2311:T-SASO>2.0.ZU;2-U
Abstract
The synthesis of tetrathiacalix[4]arene was achieved by the detertiobu tylation of p-tert-butyltetrathiacalix[4]arene. X-ray diffraction stud ies revealed that in the solid state whereas p-tert-butyltetrathiacali x[4]arene forms inclusion complexes with solvent molecules, tetrathiac alix[4]arene undergoes self-inclusion leading to trimeric units. The s ame behaviour in the crystalline phase was also demonstrated for calix [4]arene. (C) 1998 Published by Elsevier Science Ltd. All rights reser ved.