Within a study on combined hydrolysis and oxidation of starch toward D
-gluconic acid the solid acid catalyzed hydrolysis of maltose as model
compound was investigated. Acid zeolites and ion-exchange resins in t
he H-form as well as amorphous silica-aluminas were used as the catal
ysts. The optimal conditions found for maltose were applied in the hyd
rolysis of amylose and starch. It is shown that the catalysis by zeoli
tes and alumino-silicates involves homogeneous as well as heterogeneou
s catalysis.