SYNTHESIS AND STRUCTURAL STUDIES OF HYDROPHILIC MESOCYCLIC TRITHIOETHERS

Authors
SETZER WN LIOU SY EASTERLING GE SIMMONS RC GULLION LM MEEHAN EJ GRANT GJ GRAY GM
Citation
Wn. Setzer et al., SYNTHESIS AND STRUCTURAL STUDIES OF HYDROPHILIC MESOCYCLIC TRITHIOETHERS, Heteroatom chemistry, 9(2), 1998, pp. 123-128
Citations number
18
Categorie Soggetti
Chemistry
Journal title
Heteroatom chemistry → ACNP
ISSN journal
10427163
Volume
9
Issue
2
Year of publication
1998
Pages
123 - 128
Database
ISI
SICI code
1042-7163(1998)9:2<123:SASSOH>2.0.ZU;2-8
Abstract
The functionalized mesocyclic trithioethers, 1,4,7-trith iacyclodecane -9, 9-dimethanol (10S3-diMeOH), 9-methyl-1, 4, 7-trithiacyclodecane-9- carboxylic acid (Me-10S3-acid), 1,4,7-trithiacycloundecane-9,10-diol ( dihydroxy-11S3), 1,5,9-trithiacyclododecane-3,3-dimethanol (12S3-diMeO H), 3-methyl-1,5,9-trithiacyclododecane-3-carboxylic acid (Me-12S3-aci d), and 1,5,9-trithiacyclotridecane-11, 12-diol (dihydroxy-13S3), have been synthesized using the cesium dithiolate technique. The single-cr ystal X-ray structure has been determined for 3-methyl-1,5,9-trithiacy clododecane-3-carboxylic acid. The compound crystallizes in the monocl inic space group P2(1)/n, with a = 9.513(2) Angstrom, b = 5.706(1) Ang strom, c = 25.70(1) Angstrom, beta = 96.50(1)degrees, Z = 4, and R = 0 .075. (C) 1998 John Wiley & Sons, Inc.