Sc. Schurer et S. Blechert, RUTHENIUM-CATALYZED YNE-ENE CROSS METATHESIS BINDING TO SOLID SUPPORTAND CLEAVAGE BY PD-0-CATALYSIS, Synlett, (2), 1998, pp. 166
The solid phase synthesis of 1,3-dienes by yne-ene cross-metathesis in
volving binding of terminal alkenes to polystyrene resins, which conta
in propargyl ester groups, and their cleavage by Pd-0-catalysis under
C,C- or C,N-bond formation or reduction is demonstrated.