INTRAMOLECULAR ENERGY-TRANSFER IN THE ISOMERIZATION OF CYCLOBUTANONE

We report the use of the results of calculations of the rate constant for the unimolecular isomerization of cyclobutanone to test a modified version of the Zhao-Rice classical MRRKM theory. The modification con sists of using, in place of the Zhao-Rice approximation for the rate o f intramolecular energy transfer, the local Lyapunov function which de scribes the divergence of initially nearby trajectories started in the region of the cantorus. The rate of isomerization of cyclobutanone ob tained from trajectory calculations is used as the standard for compar ison of the two calculations of the rate of intramolecular energy tran sfer which are shown to yield very similar, although not identical, ra te constants. (C) 1998 Elsevier Science B.V.