DETERMINATION OF HEATS OF THE THERMAL GAS-PHASE FORMATION OF INTERMEDIATES WITH OVERLAPPING SPECTRA

Authors
BILERA IV BURAVTSEV NN KOLBANOVSKII YA
Citation
Iv. Bilera et al., DETERMINATION OF HEATS OF THE THERMAL GAS-PHASE FORMATION OF INTERMEDIATES WITH OVERLAPPING SPECTRA, Russian chemical bulletin, 47(1), 1998, pp. 25-31
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
47
Issue
1
Year of publication
1998
Pages
25 - 31
Database
ISI
SICI code
1066-5285(1998)47:1<25:DOHOTT>2.0.ZU;2-X
Abstract
The previously proposed procedure for the determination of heats of th ermal gas-phase reversible reactions using kinetic spectroscopy was ex tended for the case of the formation of two intermediate species with overlapping UV spectra. The model problem was solved, and the error of the method was estimated. Applicability of the method was shown for t he reversible formation of trimethylenemethane (TMM) and but-1-ene-2,4 -diyl from methylene-cyclopropane.