SYNTHESIS AND CRYSTAL-STRUCTURE OF TRIPHENYL[TRIS(TETRAHYDROFURAN)]YTTERBIUM, PH3YB(THF)(3)

Authors
BOCHKAREV LN ZHELEZNOVA TA SAFRONOVA AV DROZDOV MS ZHILTSOV SF ZAKHAROV LN FUKIN GK KHORSHEV SY
Citation
Ln. Bochkarev et al., SYNTHESIS AND CRYSTAL-STRUCTURE OF TRIPHENYL[TRIS(TETRAHYDROFURAN)]YTTERBIUM, PH3YB(THF)(3), Russian chemical bulletin, 47(1), 1998, pp. 165-168
Citations number
22
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
47
Issue
1
Year of publication
1998
Pages
165 - 168
Database
ISI
SICI code
1066-5285(1998)47:1<165:SACOT>2.0.ZU;2-U
Abstract
Triphenyl[tris(tetrahydrofuran)]ytterbium, Ph3Yb(THF)(3) (1), was synt hesized in high yields by the reaction of Yb with an excess of Ph2Hg o r Ph3Bi in the presence of catalytic amounts of YbI2(THF)(4) as well a s by the reaction of Ph2Yb(THF)(2) (2) with Ph2Hg or Ph3Bi. The crysta l structure of complex 1 was studied by X-ray structural analysis.