CLAISEN AROMATIC AMINO REARRANGEMENT IN THE SERIES OF FLUORINATED ANILINES

Authors
MUSTAFIN AG GIMADIEVA AR KHALILOV IN SPIRIKHIN LV FATYKHOV AA NURUSHEV RA ABDRAKHMANOV IB TOLSTIKOV GA
Citation
Ag. Mustafin et al., CLAISEN AROMATIC AMINO REARRANGEMENT IN THE SERIES OF FLUORINATED ANILINES, Russian chemical bulletin, 47(1), 1998, pp. 188-190
Citations number
6
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
47
Issue
1
Year of publication
1998
Pages
188 - 190
Database
ISI
SICI code
1066-5285(1998)47:1<188:CAARIT>2.0.ZU;2-C
Abstract
The effect of meta-substituents in the aromatic ring on the route of C laisen rearrangement of N-(pent-3-en-2-yl)-3-fluoro(or 3-trifluorometh yl, 3,4-difluoro)anilines induced by ZnCl2 was investigated. The forma tion of two possible ortho-alkenylated reaction products was observed. The ratio of these isomers depends on the nature of the acid catalyst .