The mechanistic simulations of chemical processes in forest soils requ
ire estimates of uptake and release rates of nutrients from trees, as
well as rates of microbial transformations of organic matter, chemical
weathering and solute transport within the soil profile. Among the pr
ocesses that affect the chemistry of forest soils chemical inorganic e
quilibrium processes are best understood. An appropriate presentation
of microbiological processes is lacking. Further uncertainty is introd
uced by simplistic approaches to estimate nutrient uptake by trees and
rates of chemical rock weathering. Parameters for processes are deriv
ed from studies conducted at different spatial or temporal scales and
therefore, may not always be consistent. Since kinetics cannot often b
e adequately modeled, many processes are described assuming steady-sta
te conditions, Moreover most European temperate forests are in a succe
ssional transition phase and considerably off chemical steady-state. R
easons are disturbances due to natural disasters (e.g., wild-fires) an
d anthropogenic impacts (e.g., litter raking, acidic emmissions and ma
nagement practices). Changing intensities of anthropogenic land-use an
d silvicultural methods affect the chemical status of soils for decade
s. A major constraint to modeling is the inability to properly account
for long-term patterns that arise from the longevity of forests. Resu
lts of simulation models are rather suitable to establish the boundari
es of the status of soil chemistry under defined environmental conditi
ons. Models often fail to accurately describe soil chemistry at partic
ular locations and rimes. (C) 1998 Elsevier Science B.V. All rights re
served.