ETHYLATION OF TOLUENE OVER ALUMINOPHOSPHATE MOLECULAR-SIEVES IN THE VAPOR-PHASE

Citation
C. Kannan et al., ETHYLATION OF TOLUENE OVER ALUMINOPHOSPHATE MOLECULAR-SIEVES IN THE VAPOR-PHASE, INDIAN JOURNAL OF CHEMICAL TECHNOLOGY, 5(2), 1998, pp. 65-68
Citations number
7
Categorie Soggetti
Chemistry Applied","Engineering, Chemical
ISSN journal
0971457X
Volume
5
Issue
2
Year of publication
1998
Pages
65 - 68
Database
ISI
SICI code
0971-457X(1998)5:2<65:EOTOAM>2.0.ZU;2-T
Abstract
Ethylation of toluene with ethanol over NiAPO-5, NiAPO-11, ZnAPO-5 and ZnAPO-11 was carried out in the vapour phase. The products formed fro m this reaction were ethyltoluene, diethylether, benzene and styrene. The effects of temperature, reactant ratio, time on stream and influen ce of acidity on the conversion and product distribution were discusse d. Maximum conversion was observed at 350 degrees C, but further incre ase in temperature decreased the conversion.