SYNTHESIS AND STUDY OF BINARY COMPOUNDS OF ACTINIDES AND LANTHANIDES - XXII - INTERMETALLIC COMPOUNDS OF CURIUM AND SILICON

Citation
Vm. Radchenko et al., SYNTHESIS AND STUDY OF BINARY COMPOUNDS OF ACTINIDES AND LANTHANIDES - XXII - INTERMETALLIC COMPOUNDS OF CURIUM AND SILICON, Radiochemistry, 40(1), 1998, pp. 4-6
Citations number
4
Categorie Soggetti
Chemistry Analytical","Chemistry Inorganic & Nuclear
Journal title
ISSN journal
10663622
Volume
40
Issue
1
Year of publication
1998
Pages
4 - 6
Database
ISI
SICI code
1066-3622(1998)40:1<4:SASOBC>2.0.ZU;2-U
Abstract
Two microspecimens of alloys prepared from curium-244 and silicon by h igh-tempersature deposition of the vapor of metallic curium on the pla ne silicon support were studied. Four intermetallic compounds were fou nd: orthorhombic CmSi, hexagonal Cm2Si3, and tetragonal CmSi2 and CmSi 1.88 Under alpha-radiation of Cm-244 the crystal lattices of these com pounds became amorphous in 4-8 days, The compounds with a simple cubic crystal lattice (a = 9.497 Angstrom in the initial state) belonging p robably to SiO2 were also registered,During a half-year exposure this crystal lattice is expanded by 0.8%.