An ongoing air quality monitoring program in the Czech Republic has pr
ovided nearly continuous data for the concentrations of aerosol and ga
s-phase pollutants since its inception in February 1992. In addition t
o PM-2.5 concentrations, the concentrations of sulfate, organic carbon
, elemental carbon, trace elements (Al-Pb), and polynuclear aromatic h
ydrocarbons (PAHs) were also measured. Fine particulate matter (PM-2.5
) was composed mainly of organic carbon and sulfate with smaller amoun
ts of trace metals. Coarse particle mass concentrations were typically
between 10 and 30% of PM-2.5 concentrations. The chemical composition
of emissions from power plants, residential space heating, local fact
ories, and motor vehicles was also characterized. The ambient monitori
ng and source characterization data were then used in receptor modelin
g calculations, the results of which indicate that residential space h
eating and power plant emissions accounted for most of fine particle m
ass concentrations observed during winter air pollution episodes. Moto
r vehicles, incinerators, and wind blown dust contributed to the balan
ce of the fine particle mass. Peak 24-h average TSP and SO2 concentrat
ions (1100 and 800 mu g/m(3), respectively) obtained at the main monit
oring site at Teplice in northern Bohemia during a severe air pollutio
n episode in 1993 were within a factor of 2 of smoke and SO2 concentra
tions (1800 and 1600 mu g/m(3)) measured in London during the smog epi
sode of December 5-9, 1952. That pollution episode was thought to have
contributed to a substantial increase in mortality.