N. Guilhaumou et al., P-T CONDITIONS OF SANDSTONES SILICIFICATION FROM THE BRENT-GROUP (DUNBAR, NORTH-SEA), European journal of mineralogy, 10(2), 1998, pp. 355-366
Silicification is one of the diagenetic phenomena that causes a drasti
c decrease of porosity in sandstone reservoirs. Ln several important h
ydrocarbon fields located in the Brent Province of the northern North
Sea, silicification is found together with illitisation. The present p
aper attempts to define pressure and temperature conditions of silicif
ication in the Dunbar field (Greater Alwyn, Great Britain). SEM cathod
oluminescence observations were performed on sandstones. Raman FTIR mi
croanalyses and microthermometric measurements were done on single inc
lusions precisely related to the quartz overgrowth generation. Two mai
n types of aqueous and hydrocarbon-bearing fluid inclusions are observ
ed and can be related to the beginning of the main silicification phas
e: (1) Trapping of fluid inclusions with highly variable methane conte
nts in rehealed cracks; (2) Trapping of contemporaneous aqueous and hy
drocarbon fluid inclusions, mainly at the boundary between detrital gr
ains and overgrowth. Two phase aqueous fluid inclusions homogenize bet
ween 105 and 110 degrees C in the Frontal Panel area and between 100-1
05 and 105-110 degrees C in the West Flank area depending on the well.
Salinities are between 2.5 and 4 wt% equiv. NaCl. Raman microspectrom
etric analyses and observation of earlier heterogeneous trapping sugge
st that the brine is methane-saturated in all samples with no other ga
s species detected. FTIR microspectrometry of hydrocarbon-bearing flui
d inclusions show that they contain light aliphatic mature oils (C-8-C
-10 alkane equivalent) with variable amounts of dissolved CO2. Their h
omogenization temperatures vary between 80 and 90 degrees C, depending
on the well. Since the trapped brines are in the methane-saturated H2
O-NaCl(+/-KCl) system, homogenization temperatures of aqueous inclusio
ns are equal to trapping temperatures. The trapping temperatures are 1
5 to 20 degrees C lower than the present-day formation temperatures, t
his argues against a present-day resetting of the inclusions. The dedu
ced pressure values are near 400 +/- 20 bars. Using basin modelling (G
ENEX) to match observed organic matter maturation parameters, the temp
eratures obtained from fluid inclusions correspond to a burial depth o
f 2.3 to 2.5 km sub-seafloor for the Frontal Panel and 2.4 to 2.8 km s
ub-seafloor for the West Flank. The pressure values obtained from flui
d inclusions are higher than those derived from modelling which may in
dicate the existence of overpressures in the reservoir at the time of
cementation.