HOMOGENEOUS REDUCTION OF NITROBENZENE TO ANILINE UNDER CO H2O, CATALYZED BY CIS-[RH(CO)(2)(AMINE)(2)]PF6 - THE ROLE OF THE AMINE EFFECT/

Authors
LINARES C MEDIAVILLA M PARDEY AJ BARICELLI P LONGOPARDEY C MOYA SA
Citation
C. Linares et al., HOMOGENEOUS REDUCTION OF NITROBENZENE TO ANILINE UNDER CO H2O, CATALYZED BY CIS-[RH(CO)(2)(AMINE)(2)]PF6 - THE ROLE OF THE AMINE EFFECT/, Catalysis letters, 50(3-4), 1998, pp. 183-185
Citations number
28
Categorie Soggetti
Chemistry Physical
Journal title
Catalysis letters → ACNP
ISSN journal
1011372X
Volume
50
Issue
3-4
Year of publication
1998
Pages
183 - 185
Database
ISI
SICI code
1011-372X(1998)50:3-4<183:HRONTA>2.0.ZU;2-H
Abstract
Homogeneous catalytic reduction of nitrobenzene to aniline by cis-[Rh( CO)(2)(amine)(2)]PF6 (amine = 4-picoline, 3-picoline, 2-picoline, pyri dine, 3,5-lutidine or 2,6-lutidine) in aqueous amine 2/8, v/v, P(CO) = 0.9 atm, T = 100 degrees C, [Rh] = 10 mM under water-gas shift reacti on conditions is described. The effect of various amines as additives was examined.