P. Erdmann et T. Krause, INVESTIGATIONS OF THE PRODUCTION OF RAPESEED FATTY-ACID ESTERS BY USING OF EXTRACTED OIL BY ETHANOL, Fett, 97(7-8), 1995, pp. 273-277
The most used solvent for production of alkylester of rape oil as Dies
el Fuel is methanol. Other low chain alcohols (for example ethanol) ar
e also suitable for the transesterification to produce rape oil ethyle
sters. Before the transesterification of the vegetable oil it must be
recovered by pressing and solvent extraction. In the oil industry hexa
n is used for extraction. It is possible to realize the extraction by
ethanol. The idea of work is the combination of the recovery of oil an
d the transesterification by ethanol as well as solvent and partner fo
r transesterification. In this report was investigated the possibility
of the direct transesterification of oils extracted by ethanol in a s
mall technical range to produce an ethylester of rape oil. The use of
different solvents and the transesterification of pure substances was
investigated, too. The transesterification by methanol shows better re
sults than the transesterification by ethanol. The transesterification
after the extraction by ethanol is possible. Water and undesirable fa
tty materials, however, have a negative influence on the transesterifi
cation of the mixture (oil/ethanol). Also the results of the investiga
tions show the use of the solvent extraction by ethanol will influence
the qualities of the coars meal. Consequently it is possible to produ
ce ethyl ester of rape oil as well as chemical raw materials for techn
ical, cosmetical and pharmaceutical purposes. Up to now the costs of t
his process for production of ethyl esters are very high.