J. Llorca et I. Casanova, FORMATION OF CARBIDES AND HYDROCARBONS IN CHONDRITIC INTERPLANETARY DUST PARTICLES - A LABORATORY STUDY, Meteoritics & planetary science, 33(2), 1998, pp. 243-251
The reaction between kamacite grains and H-2 + CO gas mixture has been
tested in the laboratory under experimental conditions presumed for i
nterplanetary dust particle (IDP) formation in a nebular-type environm
ent (H-2:CO = 250:1; 5 x 10(-4) atm total pressure, and 473 K). Carbon
deposition, hydrocarbon production in the C-1-C-4 range, and the form
ation of an E-carbide phase occur when well-defined model FeNi bcc all
oy (kamacite) particles are exposed to a mixture of H-2 + CO during 10
(3) h. These results strongly support the idea that gas-solid reaction
s in the solar nebula during CO hydrogenation represent a plausible sc
enario for the formation of carbides and carbonaceous materials in IDP
s, as well as for the production of hydrocarbons through Fischer-Trops
ch-type reactions.