M. Wadhwa et al., MARTIAN BASALT (SHERGOTTITE) QUEEN ALEXANDRA RANGE-94201 AND LUNAR BASALT-15555 - A TALE OF 2 PYROXENES, Meteoritics & planetary science, 33(2), 1998, pp. 321-328
We present here ion microprobe analyses of rare earth and other select
ed trace and minor elements in pyroxenes of shergottite Queen Alexandr
a Range 94201 and lunar basalt 15555. Pyroxene zonation patterns recor
d the crystallization histories of these two basaltic samples from Mar
s and the Moon, respectively, and allow a comparison of mafic melt evo
lution on these two planetary bodies. Elemental abundances and trends
in pyroxenes of these two rocks indicate that their minerals formed by
continuous, closed system fractional crystallization of their respect
ive parent melts. This further supports the idea that QUE 94201 closel
y represents the composition of a true Martian basaltic melt (McSween
el al., 1996). The main differences in pyroxene elemental zonation pat
terns in these two objects are attributed to earlier crystallization o
f whitlockite in QUE 94201 (i.e., before the Fe-rich pyroxenes) than i
n 15555 (after the Fe-rich pyroxenes). The size of Eu anomalies in pyr
oxenes of QUE 94201 is intermediate between that in pyroxenes of 15555
and the other shergottites and may imply that fO(2) conditions during
crystallization of this Martian basalt were significantly more reduci
ng than for other shergottites, although not quite as reducing as for
lunar basalts. Cerium anomalies appear to be less prevalent in pyroxen
es of QUE 94201 than other Antarctic shergottites and could be indicat
ive of lesser degree of weathering in the Antarctic.