MULTIPLE INTERNAL-REFLECTION FT-IR SPECTROSCOPY (MIRFTIRS) STUDY OF THE ELECTROCHEMICAL SYNTHESIS AND THE REDOX PROCESS OF POLY(1,5-DIAMINONAPHTHALENE)

Authors
PHAM MC OULAHYANE M MOSTEFAI M CHEHIMI MM
Citation
Mc. Pham et al., MULTIPLE INTERNAL-REFLECTION FT-IR SPECTROSCOPY (MIRFTIRS) STUDY OF THE ELECTROCHEMICAL SYNTHESIS AND THE REDOX PROCESS OF POLY(1,5-DIAMINONAPHTHALENE), Synthetic metals, 93(2), 1998, pp. 89-96
Citations number
19
Categorie Soggetti
Physics, Condensed Matter","Material Science","Polymer Sciences
Journal title
Synthetic metals → ACNP
ISSN journal
03796779
Volume
93
Issue
2
Year of publication
1998
Pages
89 - 96
Database
ISI
SICI code
0379-6779(1998)93:2<89:MIFS(S>2.0.ZU;2-E
Abstract
The electrooxidation of 1,5-diaminonaphthalene (1,5-DAN) in acidic aqu eous, methanol and organic media leads to polymer film on glassy carbo n and Pt electrodes. The in situ infrared study during film growth and X-ray photoelectron spectroscopy (XPS) analysis indicate that the pol ymer structure consists of amine (-NH-C) and imine (-N=C) units, beari ng free -NH2 groups in the chain. The polymer structure was confirmed by a multiple internal reflection FT-IR spectroscopy (MIRFTIRS) study of the film redox process and by the ability of poly(1,5-DAN) film to chelate copper ions. (C) 1998 Elsevier Science S.A. All rights reserve d.