DYNAMICAL PROCESSES BETWEEN TRIPLET SUBLEVELS OF METAL-ORGANIC PT(II)COMPOUNDS

Citation
J. Strasser et al., DYNAMICAL PROCESSES BETWEEN TRIPLET SUBLEVELS OF METAL-ORGANIC PT(II)COMPOUNDS, Journal of luminescence, 76-7, 1998, pp. 611-614
Citations number
10
Categorie Soggetti
Optics
Journal title
ISSN journal
00222313
Volume
76-7
Year of publication
1998
Pages
611 - 614
Database
ISI
SICI code
0022-2313(1998)76-7:<611:DPBTSO>2.0.ZU;2-I
Abstract
Pt(2-thpy)(2) and Pt(2-thpy) (CO)Cl are investigated as representative s for the class of platinum metal compounds with organic ligands. At T = 1.3 K, these compounds show very interesting emission rise and deca y properties due to relatively slow spin-lattice relaxations (SLR) bet ween the low-lying triplet sublevels. These properties, which depend l argely on the zero-field splittings (ZFS) of the lowest triplets, may be tuned chemically. (C) 1998 Elsevier Science B.V. All rights reserve d.