A porous and discontinuous Si3N4-based fiber coating was evaluated in
SiC/Si3N4 minicomposites by fiber push-out and fractography for debond
capabilities following high temperature exposures. The exposures cons
isted of 500 h annealing at 1350 degrees C, and 25-100 h oxidation in
wafer form at 1200-1400 degrees C. In spite of considerable microstruc
tural coarsening and/or oxidation of the coating, fiber debond and sli
ding were achieved in all cases, and at stress levels comparable to th
ose reported for tough, as-fabricated SiC/Si3N4 composites with a carb
on or boron nitride interphase. Therefore, the porous coating is expec
ted to perform better than C or BN in applications where oxidation is
inevitable. The role of porosity in accommodating and mitigating the e
ffects of oxidation is thought to be important.