The preparation and crystal structure of [ZnCl(C12H27N3)]PF6 are descr
ibed. The Zn atom has a tetrahedral environment, coordinated to three
N atoms of the triaza macrocyclic ligand and to one Cl- ion, The Zn-N
distances are in the range 2.037 (1)-2.048 (1) Angstrom, with Zn-Cl 2.
2010 (4) Angstrom.