4-HYDROXYBENZOATO-O)BIS-(NICOTINAMIDE-N)COPPER(II)

Citation
T. Hokelek et al., 4-HYDROXYBENZOATO-O)BIS-(NICOTINAMIDE-N)COPPER(II), Acta crystallographica. Section C, Crystal structure communications, 54, 1998, pp. 347-348
Citations number
10
Categorie Soggetti
Crystallography
ISSN journal
01082701
Volume
54
Year of publication
1998
Part
3
Pages
347 - 348
Database
ISI
SICI code
0108-2701(1998)54:<347:4>2.0.ZU;2-5
Abstract
The title compound, [Cu(C7H5O3)(2)(C6H6N2O)(2)(H2O)(2)], is a crystall ographically centrosymmetric complex in which pyridine N and carboxyla te and water O atoms form a tetragonally Jahn-Teller-distorted octahed ron about the Cu-II ion with bond distances of 1.956 (2), 2.011 (2) an d 2.575 (2) Angstrom. The noncoordinated carboxylate O atoms form hydr ogen bonds with the amide N and water O atoms [O ... O 2.705 (4) and O ... N 2.888(3) Angstrom].