SODIUM-HYDROGEN HEXAACETATODIRHODATE(II)

Authors
WEI XY DICKMAN MH POPE MT
Citation
Xy. Wei et al., SODIUM-HYDROGEN HEXAACETATODIRHODATE(II), Acta crystallographica. Section C, Crystal structure communications, 54, 1998, pp. 351-352
Citations number
10
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
54
Year of publication
1998
Part
3
Pages
351 - 352
Database
ISI
SICI code
0108-2701(1998)54:<351:SH>2.0.ZU;2-G
Abstract
The centrosymmetric title compound, Na(H)[Rh-2(C2H3O2)(6)], consists o f dirhodium(II) tetraacetate with two additional axial acetate ligands . Charges are balanced by a sodium ion and a disordered proton, The so dium coordination sphere includes O atoms bound equatorially to the rh odium, as well as O atoms from the axial acetates. The Rh-Rh distance is 2.3827 (5) Angstrom, Rh-O(axial) is 2.279 (2) Angstrom, and the ave rage Rh-O(equatorial) distance is 2.040 (4) Angstrom.