AN AZOMETHYLENE CARBONYLIRON COMPLEX FROM 4,4'-DIMETHYLBENZALDAZINE, RAZONE-N-1-(5-METHYLBENZYLIDENE)HEXACARBONYLDIIRON

Authors
ZACHARA J ZIMNIAK A
Citation
J. Zachara et A. Zimniak, AN AZOMETHYLENE CARBONYLIRON COMPLEX FROM 4,4'-DIMETHYLBENZALDAZINE, RAZONE-N-1-(5-METHYLBENZYLIDENE)HEXACARBONYLDIIRON, Acta crystallographica. Section C, Crystal structure communications, 54, 1998, pp. 353-355
Citations number
14
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
54
Year of publication
1998
Part
3
Pages
353 - 355
Database
ISI
SICI code
0108-2701(1998)54:<353:AACCF4>2.0.ZU;2-F
Abstract
The crystal structure of the title complex, [Fe-2(C16H16N2)(CO)(6)], c ontains two crystallographically independent molecules of the complex which have enantiomeric conformations and show notable differences in the geometry of the organic ligand. The typical Fe-Fe single bond is u nsymmetrically bridged by the N atom and by a 3-metallated 2,3-pi bond ed aromatic ring.