M. Deb et U. Sehgal, PETROLOGY, GEOTHERMOBAROMETRY AND C-O-H-S FLUID COMPOSITIONS IN THE ENVIRONS OF RAMPURA-AGUCHA ZN-(PB) ORE DEPOSIT, BHILWARA DISTRICT, RAJASTHAN, Proceedings of the Indian Academy of Sciences. Earth and planetary sciences, 106(4), 1997, pp. 343-356
The massive Zn-(Pb) sulfide ore body at Rampura-Agucha in Bhilwara dis
trict, Rajasthan, occurs within graphitic metapelites surrounded by ga
rnet-biotite-sillimanite gneiss containing concordant bodies of amphib
olite. These rocks and the sulfide ores have been studied to estimate
the pressure, temperature and fluid composition associated with upper
amphibolite facies metamorphism. Geothermobarometric calculations invo
lving garnet-biotite and garnet-hornblende pairs, as well as sphalerit
e-hexagonal pyrrhotite-pyrite and garnet-plagioclase-sillimanite-quart
z assemblages indicate that the most pervasive P-T condition during pe
ak of regional metamorphism was 650 degrees C and 6 kb, and was attain
ed between the first and second deformations in the region. Some tempe
rature-pressure estimates also cluster around 500 degrees C-5.lkb whic
h probably represent retrograde cooling during unloading. Consideratio
n of devolatilization equilibria in the C-O-H-S system at the pervasiv
e metamorphic conditions mentioned above shows that the metamorphic fl
uid was H2O-rich (X-H2O = 0.52) but also had a substantial component o
f CO2 (X-CO2 = 0.39). H2S(X-H2S = 0.043) and CH4 (X-CH4 = 0.025) were
the other important phases in the fluid. CO(X-CO = 0.002) and H-2 (X-H
2 = 0.002) were the minor phases in the fluid. It is probable that a p
art of this aqueous fluid was consumed by re-/neocrystallization of hy
drous silicate phases like chlorite during the retrogressive metamorph
ic path, so that fluid entrapped in quartz below 450 degrees C was ren
dered CO2-rich (Holler et al 1996).