C. Linares et al., HOMOGENEOUS REDUCTION OF NITROBENZENE TO ANILINE BY CO H2O, CATALYZEDBY CIS-[IR(CO)(2)(AMINE)(2)]PF6/, Boletin de la Sociedad Chilena de Quimica, 43(1), 1998, pp. 55-59
Homogeneous catalytic reduction of nitrobenzene to aniline by cis-[Ir(
CO)(2)(amine)(2)]PF6 (amine = 4-picoline, 3-picoline, 2-picoline, pyri
dine, pyridine, 3,5-lutidine or 2,6-lutidine) in aqueous amine 2/8, v/
v, P(CO) = 0.9 atm, T = 100 degrees C, [Ir] = 10 mM and substrate/Ir =
2500 under water gas shift reaction conditions is described. Addition
ally the effect of various amines as additives was examined.