H. Shirahama et al., TAUTOMERISM OF CLITIDINE, A PYRIDINE NUCLEOSIDE FROM THE POISONOUS MUSHROOM CLITOCYBE-ACROMELALGA, Heterocycles, 47(2), 1998, pp. 661-664
Tautomerism of clitidine (1a), a toxic pyridine nucleoside from the po
isonous mushroom Clitocybe acromelalga, was investigated by N-15 NMR s
pectroscopy in aqueous solution and by X-Ray crystallographic analysis
in the solid state, which showed the tautomer (1d) to be predominant
in both states.