The nature of interfacial adhesion between chemically modified sisal f
ibre and polyester resin in composites was studied in relation to the
emergence of fractographic features observed in SEM. Evidences of fibr
e fracture and residual deformed resin as river patterns attached to t
he pull-out fibre surface were supportive of improved fibre-matrix adh
esion that was caused by copolymerization between methacryl functional
attached fibre and polyester resin, Forming stable hydrophobic interp
hase region and desired compatibility of surface-modified fibre with r
esin matrix resulted in enhanced macro-mechanical properties of the co
mposites. It was also observed that the improvement in the retention o
f composite strength was appreciable even under wet conditions.