T. Friiso et al., COMPLEX PERMITTIVITY OF CRUDE OILS AND SOLUTIONS OF HEAVY CRUDE-OIL FRACTIONS, Journal of dispersion science and technology, 19(1), 1998, pp. 93-126
Dielectric spectroscopy is considered as an interesting method for det
ermination quality parameters like density, viscosity and interfacial
properties of petroleum fluids. In this paper are the mechanisms impor
tant for the dielectric properties of crude oils studied for developme
nt of new charaterising methods.Asphaltenes and resins were mixed to f
orm a total interfacially active fraction (TIAF). The complex permitti
vity of solutions of the asphaltene, resin and TIAF fractions were mea
sured for various concentrations and solvents to study the dielectric
properties of these fractions. Quantitative formula for predicting the
asphaltene content in the crude oil from measured conductivities and
permittivities were proposed. The predictability of the models for the
asphaltene content in five different crude oils varied relatively muc
h. The static permittivity of solutions of the fractions showed that t
he asphaltenes are suspended particles, whereas the other fractions ar
e molecular solutions. The operational definitions of the crude oil fr
actions result in different properties depending on the extraction pro
cedure and the properties the crude oil they are extracted from.